Dynamic Modeling and Analysis of a Disruptive Thermochemical Energy Storage Suitable for Linear Focus Solar Technologies

Abstract

The industrial sector is a significant energy consumer, primarily reliant on fossil fuels. Nevertheless, the potential of Concentrated Solar Power (CSP) technologies for decarbonizing the industry is promising and the challenges posed by variability in weather and seasons can be effectively addressed through the use of seasonal storage methods, such as Thermochemical Energy Storage (TCES). This study presents a dynamic lumped-capacitance model, implemented in Dymola, designed to simulate a continuous suspension reactor employing salt hydrates like calcium oxalate monohydrate/anhydrous. The model mainly comprised (i) heat balances, (ii) reaction kinetics for the dehydration process and (iii) a heat transfer model. Furthermore, the study delves into a comprehensive case study involving the integration of CSP and TCES into a dairy processing facility located in Spain, addressing both daily operational requirements and seasonal energy storage demands. The solar field, heating demand, and storage tanks are described in detail. The transient simulation results for July showcase the efficacy of the solar installation and sensible energy storage for day-to-day operations, resulting in a total solar contribution of 47.3%. Notably, the thermochemical energy stored during this period can cover 22.1% of the low-temperature energy demand in January. The study underscores the importance of TCES in sustainable energy systems and paves the way for further optimization, economic assessment, and expanded applications. Future work will focus on enhancing the model and incorporating additional thermochemical materials, supported by additional experimental data.