Direct Optimization for Cycle Working Fluids Using a Thermodynamic Generalized Fluid Approach

Authors

DOI:

https://doi.org/10.52825/solarpaces.v1i.762

Keywords:

Thermodynamics, Power Cycles, ORC, CO2

Abstract

Fluid blends as working fluids in solar thermal power cycles have been shown to promise an even higher efficiency than pure fluids. Rather than exploring specific blends, we propose an approach in which we directly optimize for a working fluid characterized in terms of the fluid critical point following the fundamental corresponding states principle. This direct approach allows to identify the optimal fluid one would require for given cycle boundary conditions. The approach can be applied to any given cycle; the suitable fluid selection is then performed in a second step after the desired optimal properties are identified.

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References

Cengel et al.: Thermodynamics: An Engineering Approach. McGraw-Hill Education, 2019.

Rodney Allam et al.: Demonstration of the Allam cycle: An update on the development status of a high efficiency supercritical carbon dioxide power process employing full carbon capture. Energy Procedia, 114:5948–5966, 07 2017. doi: https://doi.org/10.1016/j.egypro.2017.03.1731.

Coco-Enriquez et al.: Comparison between CO2 and other supercritical working fluids (Ethane, Xe, CH4, and N2) in line-focusing solar power plants coupled to supercritical Brayton power cycles. International Journal of Hydrogen Energy, 42(Issue 28):17611–17631, 2017, https://doi.org/10.1016/j.ijhydene.2017.02.071

Habibi et al.: Working fluid selection for regenerative supercritical Brayton cycle combined with bottoming ORC driven by molten salt solar power tower using energy-exergy analysis. Sustainable Energy Technologies and Assessments, 39:1–11, 2020, https://doi.org/10.1016/j.seta.2020.100699

Crespi et al.: Thermal Efficiency Gains Enabled by Using CO2 Mixtures in Supercritical Power Cycles. Energy, pages 5, 8–9, 2021, https://doi.org/10.1016/j.energy.2021.121899.

Valencia-Chapi et al.: Supercritical CO2 Mixtures for Advanced Brayton Power Cycles in Line-Focusing Solar Power Plants. pages 1–18, 2019, https://doi.org/10.3390/app10010055.

Bell et al.: Pure and Pseudo- pure Fluid Thermophysical Property Evaluation and the Open-Source Thermophysical Property Library CoolProp. Industrial & Engineering Chemistry Research, 53(6):2498– 2508, 2014, https://doi.org/10.1021/ie4033999

Stanley I. Sandler. Chemical, Biochemical, and Engineering Thermodynamics. Fifth edition. John Wiley and Sons, Inc., 2017, .

Kenneth S. Pitzer, David Z. Lippmann, R.F. Curl Jr., Charles M. Huggins, and Donald E. Petersen. The Volumetric and Thermodynamic Properties of Fluids. II. Compressibility Factor, Vapor Pressure and Entropy of Vaporization. Journal of the American Chemical Society, pages 3433–3440, 1955, https://doi.org/10.1021/ja01618a002.

Giorgio Soave. Equilibrium Constants From a Modified Redlich-Kwong Equation of State. Chemical Engineering Science, Volume 27(Issue 6):1197–1203, 1972, https://doi.org/10.1016/0009-2509(72)80096-4

Roland Span, Eric W. Lemmon, Richard T Jacobsen, Wolfgang Wagner, and Akimichi Yokozeki. A Reference Equation of State for the Thermodynamic Properties of Nitrogen for Temperatures from 63.151 to 1000 K and Pressures to 2200 MPa. AIP: Journal of Physical and Chemical Reference Data, pages 1375, 1380, 1382, 1385–1386, 2000, https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=907386.

P.J. Linstrom and W.G. Mallard, Eds., NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg MD, 20899, https://doi.org/10.18434/T4D303, (retrieved August 7, 2022)

Michael J. Moran, Howard N. Shapiro, Daisie D. Boettner, and Margaret B. Bailey. Fundamentals of Engineering Thermodynamics. Ninth edition. Wiley, 2018.

Basem et al.: The design of a hybrid parabolic solar dish–steam power plant: An experimental study. Energy Reports, pages 1949-1965, 2022, https://doi.org/10.1016/j.egyr.2021.11.236.

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Published

2024-03-15

How to Cite

Begay, J., & Banuti, D. (2024). Direct Optimization for Cycle Working Fluids Using a Thermodynamic Generalized Fluid Approach. SolarPACES Conference Proceedings, 1. https://doi.org/10.52825/solarpaces.v1i.762